Our “ALTERPHASIC” method is different from existing ones. The monocrystalline SiC film is grown not from above, but from inside the silicon substrate. The essence of this approach is based on the preliminary introduction of point defects into the crystal lattice of the silicon matrix, from which the frame of the future film will be assembled. The defects are the carbon atoms introduced into the interstitial positions of silicon and a vacancies formed as a result of the removal of the silicon atoms. This enables growth of very thin layer of cubic or (optionally) hexagonal silicon carbide.
Alterphasic SiC/Si templates
Alterphasic templates can be grown on standard Si wafers of p- and n-type.
Diameter - 2, 3, 4, 6 inch
Further diameter scale up is ONLY limited with size of currently used reactor chamber and Si substrates diameters available. The films are uniform across the whole surface.
Alterphasic wafer 3C-SiC/Si specification
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Method, standard |
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1. Parameters of Si substrate |
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1.1 |
Growth method |
Cz |
- |
1.2 |
Orientation |
(111) |
SEMI F26-87 |
1.3 |
Work surface orientation |
(111)±0.5° |
SEMI F26-87 |
1.3 |
Substrate thickness |
950±15 μm |
SEMI F533 |
1.4 |
Conductivity type |
p (Boron) |
- |
1.5 |
Resistivity, centre |
7-13 Ω∙cm |
SEMI F84 |
1.6 |
Diameter |
100 mm |
SEMI F613 |
1.7 |
Basic cut |
According to SEMI M1, depending on the category |
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2. Parameters of heteroepitaxial layer |
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2.1 |
Material |
SiC |
- |
2.2 |
Growth method |
Atom substitution method |
- |
2.3 |
Polytype |
3C |
- |
2.4 |
Orientation |
(111) ±0.5° |
РСА |
2.5 |
Diffractometry 3C-SiC (111) θ-2θ geometry |
Clearly intense peak of 3C-SiC(111) phase in the 2θ angle range of 30-60° No peaks of other 3C-SiC phases in the specified range |
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2.6 |
Conductivity type |
Undoped |
- |
2.7 |
Thickness |
50-500 nm |
Ellipsometry/ FT-IR spectroscopy |
2.8 |
Variation of layer thickness |
10 % max (σ/mean) |
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2.9 |
Surface type |
Si-face |
- |
3. Post-growth parameters of the working surface |
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3.1 |
Roughness (RMS, Rq) |
<3 nm |
AFM |
3.2 |
Diametral deflection |
No more than ± 15 µm |
Profilometry |
4. Post-growth control of the working surface |
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4.1 |
Contamination |
None |
Visual inspection |
4.2 |
Haze |
None |
Visual inspection |
4.3 |
Chips and scratches |
None |
Opt. microsk. |
4.4 |
Pits |
None |
Оптич. микроск. |
4.5 |
Cracks |
None |
Оптич. микроск. |
4.6 |
Epitaxial defects |
None |
Оптич. микроск. |
5. Post-growth control of the back surface |
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5.1 |
Contamination |
None |
Visual inspection |
2.2 Epitaxial heterostructures
- Thick (up to hundreds of microns) and high-quality layers of III-V semiconductor materials can be grown on Alterphasic SiC-on-Si wafers.
- Thin SiC monocrystalline layers are not destroyed with the grown nitride heterostructures (such as AlN and GaN) but elastically compressed fully adapting to the lattice of these crystals. Thus almost defect-free nitride layers are obtained on one SiC layer immediately without buffering 8-12 layers of solid AlGaN solution.
-Grown III-V structures are easy to get etched off thanks to porous layer formed inside Si substrate.