ALTERPHASIC LOGO

“ALTERPHASIC” TECHNOLOGY

Our “ALTERPHASIC” method is different from existing ones. The monocrystalline SiC film is grown not from above, but from inside the silicon substrate. The essence of this approach is based on the preliminary introduction of point defects into the crystal lattice of the silicon matrix, from which the frame of the future film will be assembled. The defects are the carbon atoms introduced into the interstitial positions of silicon and a vacancies formed as a result of the removal of the silicon atoms. This enables growth of very thin layer of cubic or (optionally) hexagonal silicon carbide.

 

Alterphasic SiC/Si templates

Alterphasic templates can be grown on standard Si wafers of p- and n-type.

Diameter - 2, 3, 4, 6 inch

Further diameter scale up is ONLY limited with size of currently used reactor chamber and Si substrates diameters available. The films are uniform across the whole surface.

 

Alterphasic wafer 3C-SiC/Si specification

 

 

Method, standard

1. Parameters of Si substrate


1.1

Growth method

Cz

-

1.2

Orientation

(111)

SEMI F26-87

1.3

Work surface orientation

(111)±0.5°

SEMI F26-87

1.3

Substrate thickness

950±15 μm

SEMI F533

1.4

Conductivity type

p (Boron)

-

1.5

Resistivity, centre

7-13 Ω∙cm

SEMI F84

1.6

Diameter

100 mm

SEMI F613

1.7

Basic cut

According to SEMI M1, depending on the category

2. Parameters of heteroepitaxial layer

2.1

Material

SiC

-

2.2

Growth method

Atom substitution method

-

2.3

Polytype

3C

-

2.4

Orientation

(111) ±0.5°

РСА

2.5

Diffractometry 3C-SiC (111) θ-2θ geometry

Clearly intense peak of 3C-SiC(111) phase in the 2θ angle range of 30-60°

No peaks of other 3C-SiC phases in the specified range

2.6

Conductivity type

Undoped

-

2.7

Thickness

50-500 nm

Ellipsometry/

FT-IR spectroscopy

2.8

Variation of layer thickness

10 % max (σ/mean)

2.9

Surface type

Si-face

-

3. Post-growth parameters of the working surface

3.1

Roughness (RMS, Rq)

<3 nm

AFM

3.2

Diametral deflection

No more than ± 15 µm

Profilometry

4. Post-growth control of the working surface

4.1

Contamination

None

Visual inspection

4.2

Haze

None

Visual inspection

4.3

Chips and scratches

None

Opt. microsk.

4.4

Pits

None

Оптич. микроск.

4.5

Cracks

None

Оптич. микроск.

4.6

Epitaxial defects

None

Оптич. микроск.

5. Post-growth control of the back surface

5.1

Contamination

None

Visual inspection


 

2.2 Epitaxial heterostructures

- Thick (up to hundreds of microns) and high-quality layers of III-V semiconductor materials can be grown on Alterphasic SiC-on-Si wafers.

- Thin SiC monocrystalline layers are not destroyed with the grown nitride heterostructures (such as AlN and GaN) but elastically compressed fully adapting to the lattice of these crystals. Thus almost defect-free nitride layers are obtained on one SiC layer immediately without buffering 8-12 layers of solid AlGaN solution.

-Grown III-V structures are easy to get etched off thanks to porous layer formed inside Si substrate.